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Durable hydrophilic SR agent "Softener SR" (for polyester)

Introduction

* Softener SR produces durable hydrophilic SR properties in naturally hydrophobic fiber such as polyester knits, weaves, yarns and nonwovens.
* Softener SR is suitable for use in sportswear and general garments requiring good perspiration absorbency, in easily-soiled work clothes and table cloths, flame-resistant curtains, and dish cloths and towels requiring water absorbency.
*

SR is an abbreviation of 'Soil Release'.
This SR effect is divided into SRM and SRD.

SR SRM (Soil Removal) Removal of dust and water/oil-based soiling during washing
SRD (Soil Redeposit) Prevention of soil redeposition during washing

Description

    Appearance : Light brown emulsion
    Main component : Special polyester polymer resin
    Ionicity : Anionic
    pH : 6.5±1 (stock solution)
    Viscosity : 1000mPa・s or lower (25゚C)
    Solubility : Dissolves readily at room temperature

Features

* Softener SR imparts wash-fast water/perspiration absorbency to normally hydrophobic polyester.
* Softener SR imparts durable SR properties (SRM and SRD) to polyester.
* Softener SR finishes polyester with a soft hand.
* Softener SR can be used simultaneously in the disperse dyeing of polyester.
* With Softener SR, causing hindrance to flame-resistant properties is unlikely.

Method of use

1) Exhaust method (for simultaneous use in the disperse dyeing of
   polyester)
1) Dyeing Disperse dyestuff x % o.w.f.
Dispersing /
leveling agent
y g/L
(New Levelin RD-10 0.3g/L)
Acetic acid pH kept in the range of 4-7
Softener SR 1.5~5 % o.w.f.
  Liquor ratio 1:10~20

2) RC (Reduction clearing) Hydrosulfite 1~2g/L
Soda ash 1~2g/L (cannot be replaced by caustic soda)
Nonionic surfactant z g/L
      Liquor ratio 1:10~20

2) Padding method


Softener SR 1.5~3% soln.
Padding → Drying (100゚C x 3min) → Setting (180゚C x 1min)
* Since padding may result in reduced colorfastness, preliminary testing is required before use.

Examples of performance

1) Exhaust method
Substrate:
PET (100%) weave made from textured yarn
Auxiliary:
Softener SR 0%
3% o.w.f.+acetic acid (pH adjusted to 4)
Treatment:
130゚C x 30min (pH 4)

2) Padding method
Substrate: PET (100%) weave made from textured yarn
Auxiliary: Softener SR 0%, 3% o.w.f.
Treatment: Padding (95% pick up) → Drying (100゚C x 3min) → Setting (180゚C x 1min)

* HL= Home Laundering, based on JIS L-0217-103
Washing agent (New Beads) 2g/L
Laundering 40゚C x 5min cold rinsing (2min x 2 times) =1 cycle
HL-0: No laundering HL-20: After 20 launderings

* SR evaluation
5: No soiling
4: Practically no soiling
3: Limited soiling
2: Some soiling
1: Soiling

SRM Properties


    (Click the image for enlargement)

Water absorption - Byreck method


    (Click the image for enlargement)

Evaluation of flame resistance (In-dyebath frame-resistant SR finishing)

  Process conditions

  Substrate: 100% polyester fabric for curtain
1) Exhaust method
(one-stage)
Agent: Softener SR --- 3 %o.w.f.
  Flame retardant --- 10 %o.w.f.
  Acetic acid --- adjusted to pH=4
Treatment: 130゚Cx 30min(pH=4)

2) Padding
method (two-stage)
Auxiliary: a common softener --- 2 %soln.
  Treatment: Padding - Drying - Setting

Auxiliaries used: B= Blank (none)
1= Flame retardant only
2= Flame retardant + Softener SR
3= Flame retardant + a common softener

Flame resistant properties (JIS L 1091A-1) 45° micro burner method

Finishing
agent
Finishing
agent
Heat
application
1 min 3 sec after
ignition
Level of
combustion
Frequency
1
2
3
1
2
Blank
(none)
Residual flame time (sec)
-
-
-
-
-
1
Afterglow time(sec)
-
-
-
-
-
Carbonated area(cm2)
Flame
retardant
only
Residual flame time (sec)
0
0
0
0
0
3
Afterglow time(sec)
0
0
0
0
0
Carbonated area(cm2)
4
4
4
4
4
Flame
retardant
+ Softener SR
Residual flame time (sec)
0
0
0
0
0
3
Afterglow time(sec)
0
0
0
0
0
Carbonated area(cm2)
4
4
5
4
5
Flame
retardant
+a common
softener
Residual flame time (sec)
-
-
-
-
-
1
Afterglow time(sec)
-
-
-
-
-
Carbonated area(cm2)

For application in substrates with the mass lower than 450g/m2

After 1 min of heat application
Blank (none)
Flame
retardant only
Flame retardant
+ Softener SR
Flame retardant
+ a common
softener

Directions for use

  1. Since cationic softeners, amino silicon softeners, fluorine/wax-based water-repellents, cationic fixing agents and cationic antistatic agents have a tendency to cause hindrance to water absorbency, preliminary testing is required for selecting the kind least likely to do so.
  2. Preliminary testing is required to verify the tarring properties of the disperse dyestuff used when adding Softener SR in the dyebath. (The use of our disperse leveling agent New Levelin RD-10 is recommended.)
  3. Avoid the use of caustic soda in reduction clearing after in-dyebath treatment of Softener SR. (Performance deteriorates due to hydrolysis of the ester bonding within Softener SR.)
  4. In order to prevent the yellowing of white (fluorescent) or very pale substrates due to nitrogen oxides, it is recommended that reduction clearing and any final finishing be conducted under acidic conditions (and the use of malic acid).
  5. Preliminary testing is required before using Softener SR to verify colorfastness and other factors relating to compatibility.

Properties of wastewater

Attribute (concentration)
BOD (1g/L)
COD (1g/L)
n-hexane (10g/L)
Measurement
57mg/L
145mg/L
13mg/L

Packaging

    18kg can
    200kg drum

Handling instructions

  1. Ensure that the workplace is well ventilated and avoid contact with the eyes and skin. Use protective clothing as required. Wash hands and face thoroughly after use.
  2. In the event of direct contact with the eyes, wash the eyes immediately under running water for 15 minutes or more, and seek prompt medical attention.
  3. In the event of swallowing, spit out immediately (but do not induce vomiting if unsuccessful), and seek prompt medical attention.
  4. In the event of inhalation, remove immediately to fresh air, rest and preserve body heat. Seek medical help if required.
  5. Use this product as soon as possible and avoid outside storage. Store in a cool, dry place at a temperature between 5-35゚C away from direct sunlight in air-tight conditions.
  6. For further details, please refer to the Material Safety Data Sheet.
While the information presented here is based on data from exhaustive in-company testing, it does not guarantee results in practical use. The description above is subject to change according to improvements in performance or specifications. There is no guarantee that any patents or legal rights are not infringed upon, with regard to the specifications for this product.
Copyright (c) 1999-2008, IS Co., Ltd. All Rights Reserved.
No reproduction or republication without written permission.
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